一(yi)塊金(jin)(jin)(jin)屬,表面看來挺光滑,可是在顯微鏡(jing)下就會發現,它的(de)(de)結構很不(bu)均(jun)勻,這就為(wei)“病(bing)從口入”大開(kai)了方(fang)便(bian)之門,因為(wei)金(jin)(jin)(jin)屬遍體都(dou)是“口”,準確一(yi)點(dian)說,不(bu)是病(bing)從口入,而是病(bing)從“皮”入了。所以(yi)金(jin)(jin)(jin)屬的(de)(de)常見病(bing)--腐蝕,一(yi)般都(dou)開(kai)始于“皮膚病(bing)”。首先(xian)是金(jin)(jin)(jin)屬“皮膚潰瘍”,然(ran)后(hou)逐漸侵入到內部(bu)。由于金(jin)(jin)(jin)屬接(jie)觸的(de)(de)物質多種多樣,“得病(bing)”的(de)(de)條件也(ye)各不(bu)相同(tong),所以(yi)金(jin)(jin)(jin)屬的(de)(de)常見病(bing)還可以(yi)分為(wei)許多種。也(ye)就是說,金(jin)(jin)(jin)屬腐蝕可以(yi)分為(wei)許多種類。
金(jin)屬(shu)腐蝕(shi)(shi)分類的(de)(de)方法很多,常(chang)見的(de)(de)一種就是(shi)(shi)根據腐蝕(shi)(shi)過(guo)程中是(shi)(shi)否(fou)有電流產生(sheng),分為化(hua)(hua)學(xue)腐蝕(shi)(shi)和電化(hua)(hua)學(xue)腐蝕(shi)(shi)兩(liang)類。化(hua)(hua)學(xue)腐蝕(shi)(shi)一般(ban)是(shi)(shi)在干燥(zao)和高(gao)溫的(de)(de)環(huan)(huan)境下發生(sheng)的(de)(de),它是(shi)(shi)金(jin)屬(shu)的(de)(de)“干熱病”;電化(hua)(hua)學(xue)腐蝕(shi)(shi)是(shi)(shi)在潮濕的(de)(de)環(huan)(huan)境下發生(sheng)的(de)(de),它是(shi)(shi)金(jin)屬(shu)的(de)(de)“風濕病”。
化(hua)學腐(fu)蝕(shi)是(shi)(shi)金(jin)屬(shu)(shu)在不(bu)導電環境(jing)中(zhong)的腐(fu)蝕(shi),它是(shi)(shi)金(jin)屬(shu)(shu)與某種(zhong)物質(zhi)直(zhi)接(jie)接(jie)觸(chu)時發生的化(hua)學反應。在化(hua)學腐(fu)蝕(shi)中(zhong),和(he)金(jin)屬(shu)(shu)接(jie)觸(chu)發生反應的物質(zhi)可以是(shi)(shi)氣體(ti),也可以是(shi)(shi)液(ye)體(ti),所以化(hua)學腐(fu)蝕(shi)又分為氣體(ti)腐(fu)蝕(shi)和(he)液(ye)體(ti)腐(fu)蝕(shi)兩種(zhong)。
在(zai)(zai)高溫下,或周圍沒有導電物(wu)質(zhi)的條件下,金屬(shu)與(yu)(yu)空氣(qi)或其(qi)他其(qi)他發(fa)生(sheng)(sheng)反應(ying)(ying),表(biao)面(mian)生(sheng)(sheng)成(cheng)(cheng)氧(yang)化(hua)(hua)物(wu)或其(qi)他化(hua)(hua)合(he)物(wu)的現象,稱為氣(qi)體(ti)腐(fu)蝕(shi)。自然(ran)界中(zhong)(zhong),氣(qi)體(ti)腐(fu)蝕(shi)的現象也是(shi)很多(duo)。例如,鐵(tie)在(zai)(zai)空氣(qi)中(zhong)(zhong)或氧(yang)氣(qi)中(zhong)(zhong)加熱時,表(biao)面(mian)會生(sheng)(sheng)成(cheng)(cheng)鐵(tie)的氧(yang)化(hua)(hua)物(wu)膜(mo);鋁(lv)在(zai)(zai)空氣(qi)中(zhong)(zhong)會與(yu)(yu)氧(yang)氣(qi)反應(ying)(ying),表(biao)面(mian)生(sheng)(sheng)成(cheng)(cheng)一層(ceng)氧(yang)化(hua)(hua)鋁(lv)薄膜(mo)。像這樣,金屬(shu)與(yu)(yu)周圍的物(wu)質(zhi)接觸發(fa)生(sheng)(sheng)反應(ying)(ying)生(sheng)(sheng)成(cheng)(cheng)了(le)化(hua)(hua)合(he)物(wu),我們就說金屬(shu)被腐(fu)蝕(shi)了(le),生(sheng)(sheng)成(cheng)(cheng)的化(hua)(hua)合(he)物(wu)(膜(mo))就是(shi)腐(fu)蝕(shi)的產物(wu)(常(chang)稱作銹)。
金(jin)屬(shu)(shu)在不導電(dian)的(de)液(ye)(ye)體(ti)(ti)里的(de)腐蝕(shi)(shi)也是一(yi)種化(hua)(hua)學腐蝕(shi)(shi),叫做(zuo)液(ye)(ye)體(ti)(ti)腐蝕(shi)(shi)。銀(yin)(yin)可與(yu)碘(dian)發生(sheng)液(ye)(ye)體(ti)(ti)腐蝕(shi)(shi)。例如把碘(dian)溶(rong)解于乙(yi)醚(mi)中(zhong),制成(cheng)碘(dian)的(de)乙(yi)醚(mi)溶(rong)液(ye)(ye)。乙(yi)醚(mi)是一(yi)種有機物(wu)(wu)(wu),不能(neng)導電(dian)。把銀(yin)(yin)塊(kuai)投入溶(rong)液(ye)(ye)中(zhong),溶(rong)解了的(de)碘(dian)能(neng)夠與(yu)銀(yin)(yin)反(fan)(fan)應,在銀(yin)(yin)的(de)表面生(sheng)產(chan)碘(dian)化(hua)(hua)銀(yin)(yin)膜。石(shi)(shi)油(you)中(zhong)往往含有硫(liu)(liu)(liu)、硫(liu)(liu)(liu)化(hua)(hua)氫(qing)(qing)及某些(xie)含硫(liu)(liu)(liu)的(de)有機物(wu)(wu)(wu),石(shi)(shi)油(you)中(zhong)還(huan)含有少(shao)量水,這(zhe)少(shao)量的(de)水一(yi)般不能(neng)與(yu)硫(liu)(liu)(liu)的(de)化(hua)(hua)合(he)物(wu)(wu)(wu)形成(cheng)導電(dian)溶(rong)液(ye)(ye),但它(ta)卻能(neng)加速硫(liu)(liu)(liu)的(de)化(hua)(hua)合(he)物(wu)(wu)(wu)與(yu)金(jin)屬(shu)(shu)發生(sheng)化(hua)(hua)學反(fan)(fan)應,成(cheng)為反(fan)(fan)應的(de)催化(hua)(hua)劑。例如,硫(liu)(liu)(liu)化(hua)(hua)氫(qing)(qing)可與(yu)鐵(tie)、鉛、銅、汞、銀(yin)(yin)等反(fan)(fan)應,生(sheng)成(cheng)這(zhe)些(xie)金(jin)屬(shu)(shu)的(de)硫(liu)(liu)(liu)化(hua)(hua)物(wu)(wu)(wu),單質硫(liu)(liu)(liu)也可與(yu)銅、汞、銀(yin)(yin)等金(jin)屬(shu)(shu)反(fan)(fan)應,所以儲存石(shi)(shi)油(you)的(de)容(rong)器(qi)上部或蓋子往往被硫(liu)(liu)(liu)化(hua)(hua)氫(qing)(qing)腐蝕(shi)(shi)。在煉油(you)廠,常(chang)采用耐硫(liu)(liu)(liu)化(hua)(hua)氫(qing)(qing)腐蝕(shi)(shi)的(de)鋁(lv)箔來(lai)保護這(zhe)些(xie)容(rong)器(qi)。
化學腐(fu)蝕(shi)比較簡單(dan),而且(qie)只(zhi)在(zai)某(mou)些特定(ding)條件下才會發(fa)生。在(zai)生產和(he)日常生活中普遍存在(zai)的(de)、破壞最嚴重的(de)是電化學腐(fu)蝕(shi),它是金屬常患(huan)的(de)“風濕病”。
電(dian)(dian)(dian)(dian)化(hua)(hua)腐(fu)(fu)(fu)蝕(shi)(shi)(shi)是(shi)(shi)指金(jin)(jin)屬(shu)(shu)與電(dian)(dian)(dian)(dian)解(jie)質溶(rong)液作用(yong)所發(fa)(fa)生(sheng)的(de)(de)腐(fu)(fu)(fu)蝕(shi)(shi)(shi)。它(ta)(ta)的(de)(de)特點(dian)是(shi)(shi)在腐(fu)(fu)(fu)蝕(shi)(shi)(shi)過程中有(you)電(dian)(dian)(dian)(dian)流產生(sheng),這(zhe)是(shi)(shi)金(jin)(jin)屬(shu)(shu)表面發(fa)(fa)生(sheng)腐(fu)(fu)(fu)蝕(shi)(shi)(shi)電(dian)(dian)(dian)(dian)池作用(yong)的(de)(de)結(jie)果(guo)(guo)。通常(chang)在電(dian)(dian)(dian)(dian)化(hua)(hua)腐(fu)(fu)(fu)蝕(shi)(shi)(shi)中規定,電(dian)(dian)(dian)(dian)極電(dian)(dian)(dian)(dian)位(wei)較低的(de)(de)金(jin)(jin)屬(shu)(shu)為陽極,電(dian)(dian)(dian)(dian)極電(dian)(dian)(dian)(dian)位(wei)較高的(de)(de)金(jin)(jin)屬(shu)(shu)為陰(yin)極。當兩種(zhong)電(dian)(dian)(dian)(dian)極電(dian)(dian)(dian)(dian)位(wei)不同(tong)的(de)(de)金(jin)(jin)屬(shu)(shu)相接觸,或同(tong)種(zhong)金(jin)(jin)屬(shu)(shu)的(de)(de)不同(tong)的(de)(de)部(bu)位(wei)具有(you)不同(tong)電(dian)(dian)(dian)(dian)極電(dian)(dian)(dian)(dian)位(wei)時(shi),它(ta)(ta)們侵(qin)入電(dian)(dian)(dian)(dian)解(jie)質溶(rong)液(潮濕(shi)氣體、海水、酸(suan)、堿、鹽的(de)(de)水溶(rong)液或土壤等)后會變(bian)形成腐(fu)(fu)(fu)蝕(shi)(shi)(shi)電(dian)(dian)(dian)(dian)池。結(jie)果(guo)(guo),作為陽極的(de)(de)(電(dian)(dian)(dian)(dian)極電(dian)(dian)(dian)(dian)位(wei)低的(de)(de))金(jin)(jin)屬(shu)(shu),由于不斷失去電(dian)(dian)(dian)(dian)子并將自己的(de)(de)離子投入溶(rong)液而(er)被(bei)腐(fu)(fu)(fu)蝕(shi)(shi)(shi),而(er)作為陰(yin)極的(de)(de)(電(dian)(dian)(dian)(dian)極電(dian)(dian)(dian)(dian)位(wei)高的(de)(de))金(jin)(jin)屬(shu)(shu)由于僅起(qi)著傳遞電(dian)(dian)(dian)(dian)子的(de)(de)作用(yong),本(ben)身沒有(you)發(fa)(fa)生(sheng)腐(fu)(fu)(fu)蝕(shi)(shi)(shi)及其他變(bian)化(hua)(hua)。