產品長期暴露在空氣中,在自然條件的作用下,可能導致材料或性能被破壞或變質,這是自然的腐蝕效果。發生腐蝕的原因往往和環境中的氧氣、溫濕度、污染物等腐蝕成分有關。其中,鹽霧腐蝕就是最常見且破壞力很大的腐蝕。 鹽霧測試的作用 鹽霧是如何腐蝕金屬材料的?這是因為鹽霧中含有氯離子,可以穿透金屬表面的氧化層和防護層,直接與金屬層發生電化學反應,引起腐蝕。而且氯離子含有一定的水合能,很容易被金屬表面的空隙吸附,并取代氧化層中的氧,把不溶的氧化物變成可溶的氯化物,使本來具有防護性能的表面層變得活潑。 既然產品可能會受到鹽霧的腐蝕,那么在出廠前,就需要評估其耐腐蝕性能,評價其使用壽命。 鹽霧測試的種類 鹽霧測試可以采用天然環境暴露或人工加速模擬鹽霧環境進行試驗。天然環境暴露是最接近真實使用情況的方法,但缺點是試驗時間太長,可能廠家無法承受其時間成本。而人工加速模擬鹽霧環境試驗則是利用鹽霧試驗箱,將產品放置于試驗箱中,模擬鹽霧環境對產品的耐鹽霧腐蝕性能進行考核。 與天然環境相比較,人工鹽霧測試可以控制鹽霧濃度,使腐蝕速度大大提高,縮短試驗時間。以目前的技術條件來說,天然環境中需要測試一年以上的產品,在人工模擬鹽霧環境條件下,只要24小時即可得到接近的效果。
鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)測試(shi)(shi)主(zhu)要包括(kuo)四種(zhong)方法,中(zhong)(zhong)(zhong)性(xing)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)、銅鹽(yan)(yan)(yan)加(jia)速醋(cu)酸(suan)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)、醋(cu)酸(suan)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)和(he)交(jiao)變鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)。 中(zhong)(zhong)(zhong)性(xing)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan),又(you)稱NSS試(shi)(shi)驗(yan)(yan),是(shi)(shi)目前應(ying)用領域(yu)最(zui)廣、出現最(zui)早(zao)的(de)(de)(de)一(yi)(yi)種(zhong)加(jia)速腐(fu)蝕試(shi)(shi)驗(yan)(yan)方法。一(yi)(yi)般采用5%的(de)(de)(de)氯(lv)(lv)化(hua)鈉鹽(yan)(yan)(yan)水(shui)溶(rong)(rong)液(ye),將(jiang)溶(rong)(rong)液(ye)PH值調在(zai)(zai)中(zhong)(zhong)(zhong)性(xing)范圍(6.5~7.2),作為(wei)噴霧(wu)(wu)(wu)(wu)(wu)使用。試(shi)(shi)驗(yan)(yan)溫(wen)度(du)控(kong)制在(zai)(zai)35℃,鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)的(de)(de)(de)沉降率應(ying)為(wei)1~2ml/80cm/h。 銅鹽(yan)(yan)(yan)加(jia)速醋(cu)酸(suan)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan),又(you)稱CASS試(shi)(shi)驗(yan)(yan),是(shi)(shi)近幾年發(fa)展起(qi)來(lai)的(de)(de)(de)一(yi)(yi)種(zhong)快速鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)腐(fu)蝕試(shi)(shi)驗(yan)(yan)。試(shi)(shi)驗(yan)(yan)溫(wen)度(du)為(wei)50℃,鹽(yan)(yan)(yan)溶(rong)(rong)液(ye)中(zhong)(zhong)(zhong)加(jia)入少量銅鹽(yan)(yan)(yan)-氯(lv)(lv)化(hua)銅,具有(you)強烈誘發(fa)腐(fu)蝕能力,腐(fu)蝕速度(du)是(shi)(shi)NSS試(shi)(shi)驗(yan)(yan)的(de)(de)(de)8倍左(zuo)右。 醋(cu)酸(suan)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan),又(you)稱ASS試(shi)(shi)驗(yan)(yan),是(shi)(shi)建立在(zai)(zai)中(zhong)(zhong)(zhong)性(xing)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)的(de)(de)(de)基(ji)礎(chu)上(shang)(shang)發(fa)展而來(lai)的(de)(de)(de)。在(zai)(zai)5%氯(lv)(lv)化(hua)鈉溶(rong)(rong)液(ye)中(zhong)(zhong)(zhong)加(jia)入冰醋(cu)酸(suan),將(jiang)溶(rong)(rong)液(ye)的(de)(de)(de)PH值降為(wei)3左(zuo)右,溶(rong)(rong)液(ye)變成(cheng)酸(suan)性(xing),最(zui)后(hou)形成(cheng)的(de)(de)(de)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)也由中(zhong)(zhong)(zhong)性(xing)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)變成(cheng)酸(suan)性(xing)。其腐(fu)蝕速度(du)是(shi)(shi)NSS試(shi)(shi)驗(yan)(yan)的(de)(de)(de)3倍左(zuo)右。 交(jiao)變鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)則是(shi)(shi)屬于綜合鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan),它的(de)(de)(de)原理是(shi)(shi)在(zai)(zai)中(zhong)(zhong)(zhong)性(xing)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)的(de)(de)(de)基(ji)礎(chu)上(shang)(shang)加(jia)恒定濕熱(re)的(de)(de)(de)試(shi)(shi)驗(yan)(yan)。主(zhu)要用于空腔(qiang)型的(de)(de)(de)整(zheng)機(ji)(ji)產(chan)品,通過潮(chao)濕環(huan)境的(de)(de)(de)滲透,使鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)腐(fu)蝕既在(zai)(zai)產(chan)品表面發(fa)生,也在(zai)(zai)產(chan)品內部發(fa)生。交(jiao)變鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)試(shi)(shi)驗(yan)(yan)將(jiang)產(chan)品環(huan)境在(zai)(zai)鹽(yan)(yan)(yan)霧(wu)(wu)(wu)(wu)(wu)和(he)濕熱(re)兩(liang)種(zhong)條件下不斷替換(huan),最(zui)后(hou)評估(gu)整(zheng)機(ji)(ji)產(chan)品的(de)(de)(de)電(dian)性(xing)能和(he)機(ji)(ji)械性(xing)能的(de)(de)(de)變化(hua)程度(du)。