不銹(xiu)鋼的爐中(zhong)釬焊一般是在(zai)某種保(bao)護(hu)性(xing)氣氛(fen)下或真空中(zhong)進行,保(bao)護(hu)氣氛(fen)有氫氣、分(fen)解氨和氬氣。


 干燥的氫氣或分解氨常用做爐中釬(han)焊不銹鋼(gang)時的還原性保護氣氛,它們可還原不(bu)銹鋼表面的氧化膜,并保護不銹鋼表面在釬焊時不再氧化。一般要求氫氣或分解氨的露點低于-40℃,但也要考慮保護氣體的露點要與釬焊溫度及母材的成分相適應。釬焊溫度越低、不銹鋼表面氧化膜越穩定,要求氫氣露點越低,見圖3-4。使用分解氨作保護氣氛時,必須保證NH3完全分解,避免殘余的NH3使不銹鋼表面氮化。


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 使(shi)用(yong)氫氣(qi)或(huo)(huo)分(fen)解氨作保護氣(qi)氛的好處是:可實(shi)現釬(han)焊(han)(han)爐的連續工(gong)(gong)作,便(bian)于大批(pi)量生(sheng)產(chan)(chan);釬(han)焊(han)(han)過程中不需使(shi)用(yong)釬(han)劑(ji),且(qie)焊(han)(han)后(hou)工(gong)(gong)件光亮(liang),無需任(ren)何(he)焊(han)(han)后(hou)工(gong)(gong)件表面清(qing)理工(gong)(gong)作;可配(pei)合選用(yong)的釬(han)料品種多(duo);在批(pi)量生(sheng)產(chan)(chan)條件下焊(han)(han)接成本(ben)低(di)。但是使(shi)用(yong)氫氣(qi)或(huo)(huo)分(fen)解氨作保護氣(qi)氛時要注(zhu)意生(sheng)產(chan)(chan)安(an)全,當(dang)空氣(qi)中混有(you)4%~74%的氫氣(qi)或(huo)(huo)12.5%~27%氨氣(qi)時,會因(yin)燃(ran)燒而產(chan)(chan)生(sheng)爆炸。


 作為惰性(xing)氣(qi)(qi)體,氬氣(qi)(qi)可用(yong)作爐中(zhong)釬焊不銹鋼(gang)(gang)時的保護(hu)氣(qi)(qi)氛。與氫氣(qi)(qi)和分解氨不同,氬氣(qi)(qi)不具有(you)還(huan)原性(xing),只是利用(yong)其(qi)惰性(xing)保護(hu)不銹鋼(gang)(gang)表面在釬焊過程(cheng)中(zhong)不氧(yang)化,所(suo)以(yi)不銹鋼(gang)(gang)進爐釬焊前必須徹底清除其(qi)表面的氧(yang)化膜,并且一般要(yao)求氬氣(qi)(qi)的露點低于-40℃。


 使用氬氣(qi)(qi)作保護(hu)氣(qi)(qi)氛(fen)(fen)一般(ban)是因(yin)(yin)為以下某(mou)(mou)種(zhong)(zhong)或多(duo)(duo)種(zhong)(zhong)原因(yin)(yin):①. 可采用含高(gao)蒸汽壓元素的(de)釬(han),如錳基釬(han)料或含錳較多(duo)(duo)的(de)釬(han)料;②. 單件或小批量釬(han)焊(han)時,設備成本低(di);③. 不銹鋼與異種(zhong)(zhong)材(cai)釬(han)焊(han)時避(bi)免某(mou)(mou)些材(cai)料與爐內(nei)氣(qi)(qi)氛(fen)(fen)的(de)反(fan)應(ying),如在(zai)含氫(qing)(qing)氣(qi)(qi)氛(fen)(fen)中釬(han)焊(han)連接不銹鋼與鈦(tai)合(he)金時,鈦(tai)金吸氫(qing)(qing)并與氫(qing)(qing)反(fan)應(ying);④. 生產(chan)過程安全。


 使用氬氣作保護氣氛時,常見的做法是將真空爐抽至高真空后(10-2~10-3Pa)充入少量氬氣,關閉爐體氣閥后升溫。或者在特制的密封容器內通人流動的氬氣,將空氣趕凈后,容器放入馬弗爐內加熱。也可在趕凈空氣后,關閉氣路,容器放人馬弗爐內加熱,但在升溫過


 程中要隨時(shi)注(zhu)意容器(qi)內(nei)(nei)的壓力(li),當(dang)容器(qi)內(nei)(nei)壓力(li)超(chao)過大氣壓較(jiao)多時(shi)應隨時(shi)放(fang)出一些氣體(ti)(ti),以保證(zheng)容器(qi)完好和(he)生產安(an)全。使(shi)用(yong)(yong)特(te)制(zhi)的容器(qi)還有另(ling)一個便利:當(dang)使(shi)用(yong)(yong)未經凈化(hua)的普通瓶裝(zhuang)氬氣時(shi),可(ke)向釬(han)焊(han)爐內(nei)(nei)通入少許BF3氣體(ti)(ti)釬(han)劑,或加入少許氟(fu)硼酸鉀(jia),氟(fu)硼酸鉀(jia)在800~900℃分解產生BF3.BF3可(ke)以去除金屬表面的氧(yang)化(hua)物(wu),促(cu)進(jin)釬(han)料(liao)的潤濕。氣體(ti)(ti)釬(han)劑的使(shi)用(yong)(yong)濃度一般(ban)控制(zhi)在0.1%~0.001%(體(ti)(ti)積(ji)分數),避免焊(han)后(hou)形(xing)成殘渣。氟(fu)化(hua)物(wu)對人體(ti)(ti)有害,要注(zhu)意工作場地(di)的通風。


 在真空爐中釬焊不銹鋼是一種常用且理想的方法。釬焊不銹鋼時一般要求真空度達到10-2~10-3Pa,并且要求真空爐的氣體泄漏率小于10-2Pa/s.使用真空爐釬焊不銹鋼的好處是:可避免不銹鋼的氧化;可避免釬焊爐內氣氛對母材的不良影響;真空爐升、降溫速度慢,工件不變形或變形量很小;無論以何種方式添加釬料均不會在接頭內形成氣孔;無需消耗保護氣體;無需氣體凈化裝置;無安全隱患;帶有充氣及快冷風扇置的真空爐同樣具有較高的生產率,并可實現釬焊與焊后工件熱處理的結合。


  在氫氣或分解氨氣氛爐中釬焊不銹鋼可使用紫銅、銅基、銀基、錳基、鎳基和金基釬料。在氬氣氛爐中釬焊不銹鋼可使用銅基、銀基、錳基、金基釬料。在真空爐中釬焊不銹鋼可采用紫銅、不含易蒸發元素(Zn、Cd)或僅含少量高蒸汽壓元素(Mn)的銅基和銀基釬料、鎳基釬料和金基釬料。使用鎳基釬料釬焊不銹鋼薄件時,要選擇對母材溶蝕傾向小的釬料。


 爐中釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)時(shi)(shi)影響釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)接(jie)(jie)頭性能,特別是(shi)力學性能的(de)主(zhu)要工(gong)(gong)藝參數(shu)包釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)溫(wen)(wen)(wen)度(du)(du)(du)、保(bao)(bao)(bao)溫(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)。釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)溫(wen)(wen)(wen)度(du)(du)(du)一(yi)(yi)般選擇在釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)液相線溫(wen)(wen)(wen)度(du)(du)(du)以上50~100℃,保(bao)(bao)(bao)溫(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)在5~10min.當工(gong)(gong)件(jian)(jian)較(jiao)大(da)時(shi)(shi),可在升溫(wen)(wen)(wen)過程(cheng)中釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)固相線溫(wen)(wen)(wen)度(du)(du)(du)以下(xia)某(mou)溫(wen)(wen)(wen)度(du)(du)(du)保(bao)(bao)(bao)溫(wen)(wen)(wen)一(yi)(yi)段時(shi)(shi)間(jian)(jian)(jian),確保(bao)(bao)(bao)工(gong)(gong)件(jian)(jian)溫(wen)(wen)(wen)度(du)(du)(du)均勻。使用鎳(nie)(nie)基釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)時(shi)(shi),除了釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)溫(wen)(wen)(wen)度(du)(du)(du)和(he)保(bao)(bao)(bao)溫(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)外,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)間(jian)(jian)(jian)隙也是(shi)接(jie)(jie)頭強度(du)(du)(du)和(he)塑性的(de)決定因素之一(yi)(yi)。圖3-5、圖3-6顯示(shi)了三種鎳(nie)(nie)基釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)不銹鋼時(shi)(shi)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)接(jie)(jie)頭強度(du)(du)(du)與釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)間(jian)(jian)(jian)隙的(de)關系。為(wei)降低(di)釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)的(de)熔點,鎳(nie)(nie)基釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)中含有(you)較(jiao)多的(de)硼(peng)(peng)(peng)、硅(gui)、磷,它們在釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)組(zu)織中以脆性的(de)硼(peng)(peng)(peng)化物(wu)、硅(gui)化物(wu)、磷化物(wu)形式存在。釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)時(shi)(shi)在一(yi)(yi)定的(de)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)溫(wen)(wen)(wen)度(du)(du)(du)和(he)保(bao)(bao)(bao)溫(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)下(xia),當釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)間(jian)(jian)(jian)隙小于某(mou)一(yi)(yi)數(shu)值(zhi),硼(peng)(peng)(peng)、硅(gui)、磷向母(mu)材(cai)擴散充(chong)分,凝固后釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)組(zu)織為(wei)鎳(nie)(nie)基固溶體,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)強度(du)(du)(du)高、塑性好,此(ci)數(shu)值(zhi)稱(cheng)作(zuo)該釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)(liao)在此(ci)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)溫(wen)(wen)(wen)度(du)(du)(du)和(he)保(bao)(bao)(bao)溫(wen)(wen)(wen)時(shi)(shi)間(jian)(jian)(jian)下(xia)的(de)最大(da)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)間(jian)(jian)(jian)隙。當釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)間(jian)(jian)(jian)隙超過最大(da)間(jian)(jian)(jian)隙,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)中硼(peng)(peng)(peng)、硅(gui)、磷向母(mu)材(cai)擴散不充(chong)分,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)中會存在脆性化合物(wu),釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)的(de)強度(du)(du)(du)和(he)塑性都會下(xia)降。而且在一(yi)(yi)定范(fan)圍內(nei),釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)越(yue)寬,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)(feng)中脆性相越(yue)多,接(jie)(jie)頭的(de)強度(du)(du)(du)和(he)塑性越(yue)低(di)。


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 在(zai)釬(han)(han)(han)(han)焊實際部件時,有時部件加工精度或(huo)裝配(pei)精度很難(nan)(nan)保證釬(han)(han)(han)(han)縫(feng)間隙很小,適當地提高釬(han)(han)(han)(han)焊溫(wen)(wen)度或(huo)延長(chang)保溫(wen)(wen)時間可(ke)增大(da)最大(da)釬(han)(han)(han)(han)焊間隙,見(jian)圖3-7。當在(zai)高溫(wen)(wen)下長(chang)時間保溫(wen)(wen)造(zao)成母材(cai)晶粒過(guo)(guo)分(fen)長(chang)大(da)或(huo)釬(han)(han)(han)(han)料對母材(cai)溶蝕過(guo)(guo)度時,也可(ke)在(zai)焊后接頭冷卻到某(mou)一較(jiao)低(di)溫(wen)(wen)度保溫(wen)(wen),通過(guo)(guo)擴散(san)消除釬(han)(han)(han)(han)縫(feng)中的脆性相而(er)增大(da)最大(da)釬(han)(han)(han)(han)焊間隙,見(jian)圖3-8。但由于磷(lin)原子較(jiao)大(da),向母材(cai)中擴散(san)困(kun)難(nan)(nan),這(zhe)些(xie)措施(shi)對Ni-Cr-P和Ni-P這(zhe)類釬(han)(han)(han)(han)料作用不大(da)。


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 爐中釬焊時為控制釬料不流到接頭外其他部位或造成工件與卡具的粘連,可在防止釬料潤濕處涂止焊劑。釬焊不銹鋼時可以用TiO2、Y2O3或云母粉與乙醇混和后做止焊劑。