按照氫脆敏感性與應變速率的關系,可以將氫致開裂分為兩大類。


1. 第一類氫脆


 氫脆的敏感性隨應變速率的增加而增加,即材料加載前內部已存在某種裂紋源,加載后在應力作用下加快了裂紋的形成與擴展。第一類氫脆包括三種形式:①. 氫腐蝕,由于氫在高溫高壓下與金屬中第二相(夾雜物和合金添加物)發生化學反應,生成高壓氣體(如CH4、SiH4)引起材料脫碳、內裂紋和鼓泡的現象;②. 氫鼓泡,過飽和的氫原子在缺陷位置(如夾雜)析出,形成氫分子,在局部造成很高的氫壓,引起表面鼓泡或內部裂紋的現象;③. 氫化物型氫脆,氫與IVB和VB族金屬有較大的親和力,氫含量較高時容易產生脆性的氫化物相,并在隨后受力時成為裂紋源,引起脆斷。


 上述三種情況將(jiang)造成金(jin)屬永久損(sun)傷(shang),使材料塑(su)性或強度降低,即使從金(jin)屬中除氫損(sun)傷(shang)也(ye)不(bu)能(neng)(neng)消除,塑(su)性或強度也(ye)不(bu)能(neng)(neng)恢(hui)復(fu),故稱(cheng)為不(bu)可(ke)逆氫脆。


2. 第(di)二類(lei)氫脆


 氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)的(de)(de)(de)敏感性(xing)(xing)(xing)隨應(ying)(ying)變速(su)(su)率增(zeng)加而(er)降低(di),即材(cai)料(liao)在加載前并不(bu)存(cun)在裂(lie)紋(wen)源,加載后(hou)在應(ying)(ying)力(li)(li)和氫(qing)(qing)(qing)(qing)的(de)(de)(de)交(jiao)互作用(yong)下(xia)逐漸形(xing)成裂(lie)紋(wen)源,最(zui)終(zhong)導致脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)斷(duan)(duan)裂(lie)。第二類氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)包括兩種形(xing)式:一(yi)是(shi)應(ying)(ying)力(li)(li)誘發(fa)氫(qing)(qing)(qing)(qing)化(hua)物型氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。在能夠形(xing)成脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)氫(qing)(qing)(qing)(qing)化(hua)物的(de)(de)(de)金(jin)屬(shu)中(zhong),當氫(qing)(qing)(qing)(qing)含量(liang)較(jiao)低(di)或氫(qing)(qing)(qing)(qing)在固溶(rong)體中(zhong)的(de)(de)(de)過飽和度(du)較(jiao)低(di)時(shi),尚不(bu)能自發(fa)形(xing)成氫(qing)(qing)(qing)(qing)化(hua)物;而(er)在應(ying)(ying)力(li)(li)作用(yong)下(xia),氫(qing)(qing)(qing)(qing)會(hui)向(xiang)應(ying)(ying)力(li)(li)集中(zhong)處(chu)富集,當氫(qing)(qing)(qing)(qing)濃度(du)超過臨(lin)界值時(shi)就會(hui)沉淀(dian)出(chu)氫(qing)(qing)(qing)(qing)化(hua)物。這(zhe)種應(ying)(ying)力(li)(li)誘發(fa)的(de)(de)(de)氫(qing)(qing)(qing)(qing)化(hua)物相變只在較(jiao)低(di)的(de)(de)(de)應(ying)(ying)變速(su)(su)率下(xia)出(chu)現,并由(you)此導致脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)斷(duan)(duan)裂(lie),一(yi)旦出(chu)現氫(qing)(qing)(qing)(qing)化(hua)物,即使(shi)卸載除(chu)氫(qing)(qing)(qing)(qing),靜止一(yi)段(duan)時(shi)間后(hou)再(zai)高速(su)(su)變形(xing),塑性(xing)(xing)(xing)也不(bu)能恢復,故也是(shi)不(bu)可逆氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。二是(shi)可逆氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。是(shi)指含氫(qing)(qing)(qing)(qing)金(jin)屬(shu)在高速(su)(su)變形(xing)時(shi)并不(bu)顯示脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing),而(er)在緩慢變形(xing)時(shi)由(you)于氫(qing)(qing)(qing)(qing)逐漸向(xiang)應(ying)(ying)力(li)(li)集中(zhong)處(chu)富集,在應(ying)(ying)力(li)(li)與氫(qing)(qing)(qing)(qing)交(jiao)互作用(yong)下(xia)裂(lie)紋(wen)形(xing)核、擴(kuo)展(zhan),最(zui)終(zhong)導致脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)的(de)(de)(de)斷(duan)(duan)裂(lie),在未形(xing)成裂(lie)紋(wen)前去(qu)除(chu)載荷,靜置一(yi)段(duan)時(shi)間后(hou)高速(su)(su)變形(xing),材(cai)料(liao)的(de)(de)(de)塑性(xing)(xing)(xing)可以得到(dao)恢復,即應(ying)(ying)力(li)(li)去(qu)除(chu)后(hou)脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)消失,因(yin)此稱為可逆氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。由(you)內氫(qing)(qing)(qing)(qing)引起(qi)(qi)的(de)(de)(de)稱可逆內氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui),由(you)外氫(qing)(qing)(qing)(qing)引起(qi)(qi)的(de)(de)(de)稱環境氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。通常所說(shuo)的(de)(de)(de)氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)主要(yao)指可逆氫(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui),是(shi)氫(qing)(qing)(qing)(qing)致開裂(lie)中(zhong)最(zui)主要(yao)、最(zui)危險的(de)(de)(de)破壞形(xing)式。